PART 1 Principles of Operation Chapter 1 Basic Concepts 1.3 1.1 Components of Cells and Batteries / 1.3 1.2 Classification of Cells and Batteries / 1.4 1.3 Operation of a Cell / 1.7 1.4 Theoretical Cell Voltage, Capacity, and Energy / 1.9 1.5 Specific Energy and Energy Density of Practical Batteries / 1.14 1.6 Upper Limits of Specific Energy and Energy Density / 1.17 Chapter 2 Electrochemical Principles and Reactions 2.1 2.2 Thermodynamic Background / 2.4 2.3 Electrode Processes / 2.5 2.4 Electrical Double-Layer Capacity and Ionic Adsorption / 2.11 2.5 Mass Transport to the Electrode Surface / 2.16 2.6 Electroanalytical Techniques / 2.20 Chapter 3 Factors Affecting Battery Performance 3.1 3.1 General Characteristics / 3.1 3.2 Factors Affecting Battery Performance / 3.1 Chapter 4 Battery Standardization 4.1 4.2 International Standards / 4.3 4.3 Concepts of Standardization / 4.4 4.4 IEC and ANSI Nomenclature Systems / 4.5 4.6 Electrical Performance / 4.9 4.8 Cross-References of ANSI IEC Battery Standards / 4.11 4.9 Listing of IEC Standard Round Primary Batteries / 4.12 4.10 Standard SLI and Other Lead-Acid Batteries / 4.13 4.11 Regulatory and Safety Standards / 4.21 Chapter 5 Battery Design 5.1 5.2 Designing to Eliminate Potential Safety Problems / 5.1 5.3 Battery Safeguards when Using Discrete Batteries / 5.7 5.4 Battery Construction / 5.10 5.5 Design of Rechargeable Batteries / 5.14 5.6 Electronic Energy Management and Display—‘‘Smart’’ Batteries / 5.18 Chapter 6 Selection and Application of Batteries 6.1 6.1 General Characteristics / 6.1 6.2 Major Considerations in Selecting a Battery / 6.2 6.3 Battery Applications / 6.3 6.4 Portable Applications / 6.8 Chapter 7 Primary Batteries—Introduction 7.3 7.1 General Characteristics and Applications of Primary Batteries / 7.3 7.2 Types and Characteristics of Primary Batteries / 7.5 7.3 Comparison of the Performance Characteristics of Primary Battery 7.4 Recharging Primary Batteries / 7.21 Chapter 8 Zinc-Carbon Batteries (Leclanche´ and Zinc Chloride Cell Systems) 8.1 8.1 General Characteristics / 8.1 8.3 Types of Cells and Batteries / 8.5 8.5 Cell Components / 8.11 8.6 Performance Characteristics / 8.17 8.7 Special Designs / 8.37 8.8 Types and Sizes of Available Cells and Batteries / 8.40 Chapter 9 Magnesium and Aluminum Batteries 9.1 9.1 General Characteristics / 9.1 9.3 Construction of Mg/MnO2 Batteries / 9.4 9.4 Performance Characteristics of Mg/MnO2 Batteries / 9.6 9.5 Sizes and Types of Mg/MnO2 Batteries / 9.12 9.6 Other Types of Magnesium Primary Batteries / 9.13 9.7 Aluminum Primary Batteries / 9.13 Chapter 10 Alkaline-Manganese Dioxide Batteries 10.1 10.1 General Characteristics / 10.1 10.3 Cell Components and Materials / 10.5 10.4 Construction / 10.10 10.5 Performance Characteristics / 10.13 10.6 Battery Types and Sizes / 10.27 10.7 Premium Zinc / Alkaline /Manganese Dioxide High-Rate Batteries / 10.29 Chapter 11 Mercuric Oxide Batteries 11.1 11.1 General Characteristics / 11.1 11.3 Cell Components / 11.3 11.5 Performance Characteristics of Zinc / Mercuric Oxide Batteries / 11.8 11.6 Performance Characteristics of Cadmium/ Mercuric Oxide Batteries / 11.13 Chapter 12 Silver Oxide Batteries 12.1 12.1 General Characteristics / 12.1 12.2 Battery Chemistry and Components / 12.2 12.3 Construction / 12.10 12.4 Performance Characteristics / 12.11 12.5 Cell Sizes and Types / 12.16 Chapter 13 Zinc/Air Batteries—Button Configuration 13.1 13.1 General Characteristics / 13.1 13.4 Performance Characteristics / 13.6 Chapter 14 Lithium Batteries 14.1 14.1 General Characteristics / 14.1 14.3 Characteristics of Lithium Primary Batteries / 14.9 14.4 Safety and Handling of Lithium Batteries / 14.17 14.5 Lithium / Sulfur Dioxide (Li /SO2) Batteries / 14.19 14.6 Lithium /Thionyl Chloride (Li /SOCl2) Batteries / 14.31 14.7 Lithium / Oxychloride Batteries / 14.49 14.8 Lithium /Manganese Dioxide (Li /MnO2) Batteries / 14.55 14.9 Lithium /Carbon Monofluoride {Li /(CF)n} Batteries / 14.72 14.10 Lithium / Iron Disulfide (Li /FeS2) Batteries / 14.84 14.11 Lithium /Copper Oxide (Li /CuO) and Lithium /Copper Oxyphosphate [Li/Cu4O(PO4)2] Cells / 14.92 14.12 Lithium / Silver Vanadium Oxide Batteries / 14.99 Chapter 15 Solid-Electrolyte Batteries 15.1 15.1 General Characteristics / 15.1 15.2 Li / LiI(Al2O3) / Metal Salt Batteries / 15.3 15.3 The Lithium / Iodine Battery / 15.9 15.4 Ag/RbAg4I5/Me4NIn,C Batteries / 15.22 Chapter 16 Reserve Batteries—Introduction 16.3 16.1 Classification of Reserve Batteries / 16.3 16.2 Characteristics of Reserve Batteries / 16.4 Chapter 17 Magnesium Water-Activated Batteries 17.1 17.1 General Characteristics / 17.1 17.3 Types of Water-Activated Batteries / 17.3 17.5 Performance Characteristics / 17.10 17.6 Battery Applications / 17.23 17.7 Battery Types and Sizes / 17.26 Chapter 18 Zinc/Silver Oxide Reserve Batteries 18.1 18.1 General Characteristics / 18.1 18.4 Performance Characteristics / 18.7 18.5 Cell and Battery Types and Sizes / 18.12 18.6 Special Features and Handling / 18.16 Chapter 19 Spin-Dependent Reserve Batteries 19.1 19.1 General Characteristics / 19.1 19.3 Design Considerations / 19.3 19.4 Performance Characteristics / 19.6 Chapter 20 Ambient-Temperature Lithium Anode Reserve Batteries 20.1 20.1 General Characteristics / 20.1 20.4 Performance Characteristics / 20.15 Chapter 21 Thermal Batteries 21.1 21.1 General Characteristics / 21.1 21.2 Description of Electrochemical Systems / 21.3 21.3 Cell Chemistry / 21.7 21.4 Cell Construction / 21.10 21.5 Cell-Stack Designs / 21.14 21.6 Performance Characteristics / 21.16 21.7 Testing and Surveillance / 21.20 21.8 New Developments / 21.20 PART 4 Secondary Batteries Chapter 22 Secondary Batteries—Introduction 22.3 22.1 General Characteristics and Applications of Secondary Batteries / 22.3 22.2 Types and Characteristics of Secondary Batteries / 22.8 22.3 Comparison of Performance Characteristics for Secondary Battery Chapter 23 Lead-Acid Batteries 23.1 23.1 General Characteristics / 23.1 23.3 Constructional Features, Materials, and Manufacturing Methods / 23.16 23.4 SLI (Automotive) Batteries: Construction and Performance / 23.35 23.5 Deep-Cycle and Traction Batteries: Construction and Performance / 23.44 23.6 Stationary Batteries: Construction and Performance / 23.54 23.7 Charging and Charging Equipment / 23.67 23.8 Maintenance Safety, and Operational Features / 23.75 23.9 Applications and Markets / 23.81 Chapter 24 Valve Regulated Lead-Acid Batteries 24.1 24.1 General Characteristics / 24.1 24.3 Cell Construction / 24.4 24.4 Performance Characteristics / 24.8 24.5 Charging Characteristics / 24.27 24.6 Safety and Handling / 24.39 24.7 Battery Types and Sizes / 24.40 24.8 Applications of VRLA Batteries to Uninterruptible Power Supplies / 24.43 Chapter 25 Iron Electrode Batteries 25.1 25.1 General Characteristics / 25.1 25.2 Chemistry of Nickel-Iron Batteries / 25.2 25.3 Conventional Nickel-Iron Batteries / 25.4 25.4 Advanced Nickel-Iron Batteries / 25.13 25.5 Iron / Air Batteries / 25.16 25.6 Silver-Iron Battery / 25.19 25.7 Iron Materials as Cathodes / 25.23 Chapter 26 Industrial and Aerospace Nickel-Cadmium Batteries 26.1 26.4 Performance Characteristics / 26.9 26.5 Charging Characteristics / 26.14 26.6 Fiber Nickel-Cadmium (FNC) Battery Technology / 26.15 26.7 Manufacturers and Market Segments / 26.24 26.8 Applications / 26.28 Chapter 27 Vented Sintered-Plate Nickel-Cadmium Batteries 27.1 27.1 General Characteristics / 27.1 27.4 Performance Characteristics / 27.7 27.5 Charging Characteristics / 27.16 27.6 Maintenance Procedures / 27.20 27.8 Cell and Battery Designs / 27.26 Chapter 28 Portable Sealed Nickel-Cadmium Batteries 28.1 28.1 General Characteristics / 28.1 28.4 Performance Characteristics / 28.6 28.5 Charging Characteristics / 28.20 28.6 Special-Purpose Batteries / 28.26 28.7 Battery Types and Sizes / 28.32 Chapter 29 Portable Sealed Nickel-Metal Hydride Batteries 29.1 29.1 General Characteristics / 29.1 29.4 Discharge Characteristics / 29.7 29.5 Charging Sealed Nickel-Metal Hydride Batteries / 29.21 29.6 Cycle and Battery Life / 29.29 29.7 Proper Use and Handling / 29.32 29.8 Applications / 29.32 29.9 Battery Types and Manufacturers / 29.32 Chapter 30 Propulsion and Industrial Nickel-Metal Hydride Batteries 30.1 30.2 General Characteristics / 30.2 30.5 EV Battery Packs / 30.14 30.6 HEV Battery Packs / 30.16 30.7 Fuel Cell Startup and Power Assist / 30.18 30.8 Other Applications / 30.18 30.9 Discharge Performance / 30.22 30.10 Charge Methods / 30.29 30.11 Thermal Management / 30.30 30.12 Electrical Isolation / 30.31 30.13 Development Targets / 30.32 Chapter 31 Nickel-Zinc Batteries 31.1 31.1 General Characteristics / 31.1 31.3 Cell Components / 31.3 31.4 Construction / 31.12 31.5 Performance Characteristics / 31.17 31.6 Charging Characteristics / 31.25 31.7 Applications / 31.29 31.8 Handling and Storage / 31.35 Chapter 32 Nickel-Hydrogen Batteries 32.1 32.1 General Characteristics / 32.1 32.3 Cell and Electrode-Stack Components / 32.3 32.4 Ni-H2 Cell Construction / 32.6 32.5 Ni-H2 Battery Design / 32.11 32.6 Applications / 32.16 32.7 Performance Characteristics / 32.19 32.8 Advanced Designs / 32.26 Chapter 33 Silver Oxide Batteries 33.1 33.1 General Characteristics / 33.1 33.3 Cell Construction and Components / 33.4 33.4 Performance Characteristics / 33.8 33.5 Charging Characteristics / 33.20 33.6 Cell Types and Sizes / 33.22 33.7 Special Features and Handling / 33.25 33.8 Applications / 33.25 33.9 Recent Developments / 33.28 Chapter 34 Rechargeable Lithium Batteries (Ambient Temperature) 34.1 34.1 General Characteristics / 34.1 34.3 Characteristics of Lithium Rechargeable Batteries / 34.17 34.4 Characteristics of Specific Rechargeable Lithium Metal Batteries / 34.25 Chapter 35 Lithium-Ion Batteries 35.1 35.1 General Characteristics / 35.1 35.3 Construction of Cylindrical and Prismatic Li-Ion Cells and Batteries / 35.31 35.4 Li-Ion Battery Performance / 35.35 35.5 Charge Characteristics of Li-Ion Batteries / 35.67 35.6 Safety Testing of Cylindrical C/LiCoO2 Batteries / 35.70 35.7 Polymer Li-Ion Batteries / 35.71 35.8 Thin-Film, Solid-State Li-Ion Batteries / 35.85 35.9 Conclusions and Future Trends / 35.90 Chapter 36 Rechargeable Zinc/Alkaline/Manganese Dioxide Batteries 36.1 36.1 General Characteristics / 36.1 36.5 Charge Methods / 36.13 36.6 Types of Cells and Batteries / 36.17 PART 5 Advanced Batteries for Electric Vehicles and Emerging Chapter 37 Advanced Batteries for Electric Vehicles and Emerging Applications—Introduction 37.3 37.1 Performance Requirements for Advanced Rechargeable Batteries / 37.3 37.2 Characteristics and Development of Rechargeable Batteries for Emerging 37.3 Near-Term Rechargeable Batteries / 37.17 37.4 Advanced Rechargeable Batteries—General Characteristics / 37.18 37.5 Refuelable Batteries and Fuel Cells—An Alternative to Advanced Rechargeable Batteries / 37.23 Chapter 38 Metal/Air Batteries 38.1 38.1 General Characteristics / 38.1 38.3 Zinc / Air Batteries / 38.6 38.4 Aluminum/ Air Batteries / 38.30 38.5 Magnesium/ Air Batteries / 38.44 38.6 Lithium / Air Batteries / 38.46 Chapter 39 Zinc/Bromine Batteries 39.1 39.1 General Characteristics / 39.1 39.2 Description of the Electrochemical System / 39.2 39.5 Tradeoff Considerations / 39.10 39.6 Safety and Hazards / 39.11 39.7 Applications and System Designs / 39.11 39.8 Developments and Projections / 39.20 Chapter 40 Sodium-Beta Batteries 40.1 40.1 General Characteristics / 40.1 40.2 Description of the Electrochemical Systems / 40.3 40.3 Cell Design and Performance Characteristics / 40.7 40.4 Battery Design and Performance Characteristics / 40.17 40.5 Applications / 40.28 Chapter 41 Lithium/Iron Sulfide Batteries 41.1 41.1 General Characteristics / 41.1 41.2 Description of Electrochemical System / 41.3 41.4 Performance Characteristics / 41.6 41.5 Applications and Battery Designs / 41.15 PART 6 Portable Fuel Cells Chapter 42 Portable Fuel Cells—Introduction 42.3 42.1 General Characteristics / 42.3 42.2 Operation of the Fuel Cell / 42.5 42.3 Sub-Kilowatt Fuel Cells / 42.9 42.4 Innovative Designs for Low Wattage Fuel Cells / 42.12 Chapter 43 Small Fuel Cells (Less than 1000 Watts) 43.1 43.2 Applicable Fuel Cell Technologies / 43.2 43.3 System Requirements / 43.4 43.4 Fuel Processing and Storage Technologies / 43.7 43.5 Fuel Cell Stack Technology / 43.12 43.6 Hardware and Performance / 43.14 B. Standard Reduction Potentials B.1 C. Electrochemical Equivalents of Battery Materials C.1 D. Standard Symbols and Constants D.1 E. Conversion Factors E.1 G. Battery Manufacturers and R&D Organizations G.1 |