Actually in real life what we simulate in the simulators we don't get exactly that in the physical design.So as every thing is probabilistic you have to ensure that the chipyou fabricate should work in all process corners. .They are what you have listed.Now suppose you have a speed spec.So if the functionality is achieved in all specs then u have to simulate in Slow-Slow corner to figure out the worst case speed.Similarly for power spec u simulate in FF corner as in that corner the Current is maximum as the transistors have low Vt there.